Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes

Publikation: Beiträge in ZeitschriftenZeitschriftenaufsätzeForschungbegutachtet

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Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes. / Corey, Elias James; Rücker, Christoph.
in: Tetrahedron Letters, Jahrgang 23, Nr. 7, 1982, S. 719-722.

Publikation: Beiträge in ZeitschriftenZeitschriftenaufsätzeForschungbegutachtet

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@article{37ce2445777849ceaf3d8bc7a07b939b,
title = "Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes",
abstract = "Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.",
keywords = "Chemistry",
author = "Corey, {Elias James} and Christoph R{\"u}cker",
note = "Funding Information: cyclohexyl . The erythro stereochemistry of the adduct 8 was supported by (1) the pmr spectrum",
year = "1982",
doi = "10.1016/S0040-4039(00)86930-0",
language = "English",
volume = "23",
pages = "719--722",
journal = "Tetrahedron Letters",
issn = "1873-3581",
publisher = "Elsevier B.V.",
number = "7",

}

RIS

TY - JOUR

T1 - Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes

AU - Corey, Elias James

AU - Rücker, Christoph

N1 - Funding Information: cyclohexyl . The erythro stereochemistry of the adduct 8 was supported by (1) the pmr spectrum

PY - 1982

Y1 - 1982

N2 - Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.

AB - Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.

KW - Chemistry

UR - http://www.scopus.com/inward/record.url?scp=0000997935&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)86930-0

DO - 10.1016/S0040-4039(00)86930-0

M3 - Journal articles

VL - 23

SP - 719

EP - 722

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 1873-3581

IS - 7

ER -

DOI