Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes
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In: Tetrahedron Letters, Vol. 23, No. 7, 1982, p. 719-722.
Research output: Journal contributions › Journal articles › Research › peer-review
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TY - JOUR
T1 - Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes
AU - Corey, Elias James
AU - Rücker, Christoph
N1 - Funding Information: cyclohexyl . The erythro stereochemistry of the adduct 8 was supported by (1) the pmr spectrum
PY - 1982
Y1 - 1982
N2 - Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.
AB - Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.
KW - Chemistry
UR - http://www.scopus.com/inward/record.url?scp=0000997935&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(00)86930-0
DO - 10.1016/S0040-4039(00)86930-0
M3 - Journal articles
VL - 23
SP - 719
EP - 722
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 1873-3581
IS - 7
ER -