Professorship for Sustainable Chemistry and Material Resources

Organisational unit: Section

Organisation profile

RESEARCH AND TEACHING

Chair for Sustainable Chemistry and Material Resources

We research and train in the field of sustainable chemistry and pharmacy.

We focus on environmental questions as well as on sustainable questions going beyond that such as social and ecological aspects in the context of the life cycle of chemical substances and products. This includes the extraction of raw material, its use as well as the fate after its use. We are also interested in the material flow associated with the extraction and use of the raw material. On top of the experimental work and modeling, we also develop concepts as for example Benign by Design intended dissipation.

Our research and teaching is carried out on an intra- and transdisciplinary scale within the Faculty of Sustainability together with national and international co-operations.

 

Topics

We are interested in environmental affairs and all questions concerning the sustainability within the context of the life cycle of chemicals, starting with the raw material itself and going on to the synthesis, the use to end up with the environmental fate of chemical substances and products after their use. Beyond the chemical substances and products themselves, we are also interested in the associated material flows, especially when it comes to the so-called strategic resources (e. g. phosphate, seldom metals).

We investigate the fate (e. g. identification of relevant sources) in the environment as well as the spread and the behavior of chemicals (e. g. spread, biological and photochemical degradation) in the aquatic environment in the sense of a sustainable water management. This is why we want to record their effects (e. g. genotoxicity, mutagenity, and bacteria toxicity).At present we are focusing on pesticides, pharmaceuticals, textile auxiliary agents and nanoparticles.

Service offers

Examination of (bio)-degradability of chemicals and pharmaceuticals  
according to OECD/DIN/ISO and others:
 
•    
Closed Bottle-Test (OECD 301 D)
•    Manometric Respirometry (OECD 301 F)
•    Zahn-Wellens-Test (OECD 302 B)
•    Waste water treatment plant simulation (OECD 303 A)
•    Water Sediment Test
•    Photochemical degradation
•    Photocatalytic degradation
•    Electro coalugation
•    and other
 
Toxicity
Acute and chronic toxicity in bacteria:
•    Luminescent bacteria test with Vibrio fischeri (30 minutes and 20h)
•    Growth-inhibition test with Pseudomonas putida (16h) and Vibrio fischeri (20h)
•    Growth-inhibition test with Enteroccus faecalis      

Genotoxicity:
•    Ames-Test with Salmonella typhimurium TA 98/TA 100
•    Umu-Test with Salmonella typhimurium TA 1535/ psK 1002
•    Mikronucleus-Test with CHO-Cells by FACS-Analysis
•    Green Screen-Assay with TK6-cells

Chemical informatics
Structure property relationships
•    Calculation of physicochemical properties of molecules
•    Calculation of quantum chemical parameters of molecules
•    Calculation of toxicity and mutagenicity
•    Calculation of the biological degradation
•    Calculation of metabolites (mammalia bacteria)
•    Targeted design of chemicals and pharmaceuticals
•    Support in purchasing decisions
•    Product optimization
•    REACH
 
Water flux based reactive mass transport modelling and assessment
•    Spatio-temporal analysis of discharge and water quality (R-Statistics, SigmaPlot, ArcGIS)
•    Assessment of water quality by combined water quality and quantity indices (WQI, WQQI, WAI)
•    Water quality modelling in lakes and reservoirs in 1D, 2D and 3D (LAC, MOHID Water, Ce-qual)
•    Catchment modelling of hydrology, erosion and sedimenttransport, phosphorus discharge, pesticides and transformation product discharge (ZIN-Sed, MOHID Land, reservoir models)
•    River channel modelling of water, sediment, phosphorus, pesticide and transformation product discharge (ZIN-Sed, MOHID Stream)
•    Scenario modelling and assessment
•    System analysis and management assessment
•    Integrated water ressources management
   
Analytics
•    Liquid chromatography coupled to ion trap mass spectrometry
•    HPLC with UV and fluorescence detection
•    Gas chromatography coupled to mass spectrometry
•    Ion chromatography

  1. Journal articles › Research › Peer-reviewed
  2. Published

    Optimization and validation of an HPLC-UV method for determination of tranexamic acid in a dosage form and in human urine.

    Hadad, G. M., El-Gindy, A. & Mahmoud, W. M. M., 09.2007, In: Chromatographia. 66, 5-6, p. 311-317 7 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  3. Published

    Optimization and Validation of an LC Method for the Determination of Cefdinir in Dosage Form and Human Urine

    Hadad, G. M., Emara, S. & Mahmoud, W. M. M., 12.2009, In: Chromatographia. 70, 11/12, p. 1593–1598 6 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  4. Published

    Oxidation-coagulation of β-blockers by K2Fe(VI)O4 in hospital wastewater: Assessment of degradation products and biodegradability

    Wilde, M. L., Mahmoud, W. M. M., Kümmerer, K. & Martins, A. F., 01.05.2013, In: The Science of The Total Environment. 452-453, p. 137-147 11 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  5. Published

    PharmCycle: a holistic approach to reduce the contamination of the aquatic environment with antibiotics by developing sustainable antibiotics, improving the environmental risk assessment of antibiotics, and reducing the discharges of antibiotics in the wastewater outlet

    Andrae, J., Beyer, F., Cornelissen, G., Einfeldt, J., Heseding, J., Kuemmerer, K., Oelkers, K. & Floeter, C., 01.12.2018, In: Environmental Sciences Europe. 30, 1, 15 p., 24.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  6. Published

    Photodegradation of micropollutants using V-UV/UV-C processes: Triclosan as a model compound

    Alfiya, Y., Friedler, E., Westphal, J., Olsson, O. & Dubowski, Y., 01.12.2017, In: The Science of The Total Environment. 601-602, p. 397-404 8 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  7. Published

    Photodegradation of the antineoplastic cyclophosphamide: A comparative study of the efficiencies of UV/H2O2, UV/Fe(2+)/H2O2 and UV/TiO2 processes

    Lutterbeck, C. A., Machado, E. L. & Kümmerer, K., 01.02.2015, In: Chemosphere. 120, p. 538-546 9 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  8. Published
  9. Published

    Photodegradation, Photocatalytic and Aerobic Biodegradation of Sulfisomidine and Identification of Transformation Products By LC–UV-MS/MS

    Sleman, F., Mahmoud, W. M. M., Schubert, R. & Kümmerer, K., 11.2012, In: Clean - Soil, Air, Water. 40, 11, p. 1244-1249 6 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  10. Published
  11. Published

    Photolysis of sulfamethoxypyridazine in various aqueous media: Aerobic biodegradation and identification of photoproducts by LC-UV-MS/MS

    Khaleel, N. D. H., Mahmoud, W. M. M., Hadad, G. M., Abdel-Salam, R. A. & Kümmerer, K., 15.01.2013, In: Journal of Hazardous Materials. 244-245, p. 654-661 8 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  12. Published

    Photolytic transformation products and biological stability of the hydrological tracer Uranine

    Gutowski, L., Olsson, O., Lange, J. & Kümmerer, K., 15.11.2015, In: The Science of The Total Environment. 533, p. 446-453 8 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  13. Published

    Physico-chemical characteristics affect the spatial distribution of pesticide and transformation product loss to an agricultural brook

    Gassmann, M., Olsson, O., Stamm, C., Weiler, M. & Kümmerer, K., 01.11.2015, In: The Science of The Total Environment. 532, p. 733-743 11 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  14. Published

    Physicochemical properties and biodegradability of organically functionalized colloidal silica particles in aqueous environment

    Schneider, M., Meder, F., Haiß, A., Treccani, L., Rezwan, K. & Kümmerer, K., 03.2014, In: Chemosphere. 99, p. 96-101 6 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  15. Published

    Possible underestimations of risks for the environment due to unregulated emissions of biocides from households to wastewater

    Wieck, S., Olsson, O. & Kümmerer, K., 01.09.2016, In: Environmental international. 94, p. 695-705 11 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  16. Published

    Priming of CD8+ T-cell responses after DNA immunization is impaired in TLR9- and MyD88-deficient mice.

    Pavlenko, M., Leder, C., Moreno, S., Levitsky, V. & Pisa, P., 21.08.2007, In: Vaccine. 25, 34, p. 6341-6347 7 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  17. Published
  18. Published

    Putting sustainable chemistry and resource use into context: The role of temporal diversity

    Weiser, A., Lang, D. J. & Kümmerer, K., 01.06.2017, In: Sustainable Chemistry and Pharmacy. 5, p. 105-114 10 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  19. Published

    Qualitative environmental risk assessment of photolytic transformation products of iodinated X-ray contrast agent diatrizoic acid

    Rastogi, T., Leder, C. & Kümmerer, K., 01.06.2014, In: The Science of The Total Environment. 482-483, 1, p. 378-388 11 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  20. Published

    Quantum Chemical Calculation and Evaluation of Partition Coefficients for Classical and Emerging Environmentally Relevant Organic Compounds

    Salthammer, T., Grimme, S., Stahn, M., Hohm, U. & Palm, W. U., 04.01.2022, In: Environmental Science and Technology. 56, 1, p. 379-391 13 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  21. Published

    Quantum chemical calculation of the vapor pressure of volatile and semi volatile organic compounds

    Stahn, M., Grimme, S., Salthammer, T., Hohm, U. & Palm, W-U., 03.10.2022, In: Environmental Sciences: Processes & Impacts. 24, 11, p. 2153-2166 14 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  22. Published
  23. Published

    Recalcitrant pharmaceuticals in the aquatic environment: A comparative screening study of their occurrence, formation of phototransformation products and their in vitro toxicity

    Bergheim, M., Gminski, R., Spangenberg, B., Dȩbiak, M., Bürkle, A., Mersch-Sundermann, V., Kümmerer, K. & Gieré, R., 2014, In: Environmental Chemistry. 11, 4, p. 431-444 14 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  24. Published

    Reducing aquatic micropollutants – Increasing the focus on input prevention and integrated emission management

    Kümmerer, K., Dionysiou, D. D., Olsson, O. & Fatta-Kassinos, D., 20.02.2019, In: Science of the Total Environment. 652, p. 836-850 15 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  25. Published

    Reducing Environmental Pollution by Antibiotics through Design for Environmental Degradation

    Leder, C., Suk, M., Lorenz, S., Rastogi, T., Pfeifer, C., Kietzmann, M., Jonas, D., Buck, M., Pahl, A. & Kümmerer, K., 19.07.2021, In: ACS Sustainable Chemistry & Engineering. 9, 28, p. 9358–9368 11 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  26. Published

    Release of monomers from four different composite materials after halogen and LED curing

    Polydorou, O., König, A., Altenburger, M. J., Wolkewitz, M., Hellwig, E. & Kümmerer, K., 01.10.2011, In: American Journal of Dentistry. 24, 5, p. 315-321 7 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  27. Published

    Reliving the past in a changed environment: Hydropower ambitions, opportunities and constraints in Tajikistan

    Wegerich, K., Olsson, O. & Froebrich, J., 01.07.2007, In: Energy Policy. 35, 7, p. 3815-3825 11 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  28. Published

    Removal of dexamethasone from aqueous solution and hospital wastewater by electrocoagulation

    Arsand, D. R., Kümmerer, K. & Martins, A. F., 15.01.2013, In: The Science of The Total Environment. 443, p. 351-357 7 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  29. Published

    Removal of the anti-cancer drug methotrexate from water by advanced oxidation processes: Aerobic biodegradation and toxicity studies after treatment

    Lutterbeck, C. A., Baginska, E., Machado, Ê. L. & Kümmerer, K., 12.2015, In: Chemosphere. 141, p. 290-296 7 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  30. Published

    Response to David B. Brooks

    Wegerich, K. & Olsson, O., 05.2011, In: Water International. 36, 3, p. 410-413 4 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  31. Published

    River flow regime and snow cover of the Pamir Alay (Central Asia) in a changing climate

    Chevallier, P., Pouyaud, B., Mojaisky, M., Bolgov, M., Olsson, O., Bauer, M. & Froebrich, J., 08.2014, In: Hydrological Sciences Journal. 59, 8, p. 1491-1506 16 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  32. Published

    Semi-micro reflux procedure for minimization of chloride interference by COD determination.

    Martins, A. F., de Jesus, L. E. W., Vendruscolo, N., Vasconcelos, T. G. & Wilde, M. L., 25.01.2008, In: Clean - Soil, Air, Water. 36, 1, p. 66-69 4 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  33. Published

    Sensory Perception of Non-Deuterated and Deuterated Organic Compounds

    Salthammer, T., Monegel, F., Schulz, N., Uhde, E., Grimme, S., Seibert, J., Hohm, U. & Palm, W. U., 13.01.2021, In: Chemistry - A European Journal. 27, 3, p. 1046-1056 11 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  34. Published

    Simultaneous Determination of 11 Sulfonamides by HPLC–UV and Application for Fast Screening of Their Aerobic Elimination and Biodegradation in a Simple Test

    Mahmoud, W. M. M., Khaleel, N. D. H., Hadad, G. M., Abdel-Salam, R. A., Haiß, A. & Kümmerer, K., 09.2013, In: Clean - Soil, Air, Water. 41, 9, p. 907-916 10 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  35. Published

    Sources and pathways of biocides and their transformation products in urban storm water infrastructure of a 2 ha urban district

    Linke, F., Olsson, O., Preusser, F., Kümmerer, K., Schnarr, L., Bork, M. & Lange, J., 20.08.2021, In: Hydrology and Earth System Sciences. 25, 8, p. 4495-4512 18 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  36. Published

    Spatial trends and ecotoxic risk assessment of selected pharmaceuticals in sediments from Lake Victoria, Uganda, East Africa

    Nantaba, F., Wasswa, J., Kylin, H., Bouwman, H., Palm, W-U. & Kümmerer, K., 01.01.2024, In: Science of the Total Environment. 906

    Research output: Journal contributionsJournal articlesResearchpeer-review

  37. Published

    Species Identification of Bacteria and Fungi from Solid and Liquid Culture Media by MALDI-TOF Mass Spectrometry

    Reich, M., Bosshard, P. P., Stark, M., Beyser, K. & Borgmann, S., 22.01.2013, In: Journal of Bacteriology & Parasitology. 4, S5, 8 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  38. Published

    Spray-dried chitosan-metal microparticles for ciprofloxacin adsorption: Kinetic and equilibrium studies

    Reynaud, F., Tsapis, N., Deyme, M., Vasconcelos, T. G., Gueutin, C., Guterres, S. S., Pohlmann, A. R. & Fattal, E., 21.08.2011, In: Soft Matter. 7, 16, p. 7304-7312 9 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  39. Published
  40. Published

    Sustainable chemistry and the international sustainable chemistry collaborative centre ISC 3

    Elschami, M., Kümmerer, K. & Schneidewind, U., 01.01.2018, In: GAIA. 27, 2, p. 247-249 3 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  41. Published

    Synthesis of Room-Temperature Ionic Liquids with the Weakly Coordinating [Al(ORF)(4)](-) Anion (R-F = C(H)(CF3)(2)) and the Determination of Their Principal Physical Properties

    Bulut, S., Klose, P., Huang, M-M., Weingartner, H., Dyson, P. J., Laurenczy, G., Friedrich, C., Menz, J., Kummerer, K. & Krossing, I., 22.11.2010, In: Chemistry - A European Journal. 16, 44, p. 13139-13154 16 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  42. Published

    Synthesis, self-assembly, bacterial and fungal toxicity, and preliminary biodegradation studies of a series of L-phenylalanine-derived surface-active ionic liquids

    Kapitanov, I. V., Jordan, A., Karpichev, Y., Spulak, M., Perez, L., Kellett, A., Kümmerer, K. & Gathergood, N., 07.04.2019, In: Green Chemistry . 21, 7, p. 1777-1794 18 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  43. Published

    Targeted metabolomics of pellicle and saliva in children with different caries activity

    Schulz, A., Lang, R., Behr, J., Hertel, S., Reich, M., Kümmerer, K., Hannig, M., Hannig, C. & Hofmann, T., 01.12.2020, In: Scientific Reports. 10, 1, 11 p., 697.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  44. Published

    Temporal dynamics and ecotoxicological risk assessment of personal care products, phthalate ester plasticizers, and organophosphorus flame retardants in water from Lake Victoria, Uganda

    Nantaba, F., Palm, W. U., Wasswa, J., Bouwman, H., Kylin, H. & Kümmerer, K., 01.01.2021, In: Chemosphere. 262, 11 p., 127716.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  45. Published

    Temporal variations of perfluoroalkyl substances and polybrominated diphenyl ethers in alpine snow

    Kirchgeorg, T., Dreyer, A., Gabrieli, J., Kehrwald, N., Sigl, M., Schwikowski, M., Boutron, C., Gambaro, A., Barbante, C. & Ebinghaus, R., 01.07.2013, In: Environmental Pollution. 178, p. 367-374 8 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  46. Published

    Tetrabutylammonium prolinate-based ionic liquids: A combined asymmetric catalysis, antimicrobial toxicity and biodegradation assessment

    Ferlin, N., Courty, M., Van Nhien, A. N., Gatard, S., Pour, M., Quilty, B., Ghavre, M., Haiß, A., Kümmerer, K., Gathergood, N. & Bouquillon, S., 28.12.2013, In: RSC Advances. 3, 48, p. 26241-26251 11 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  47. Published

    The 3 rd green & sustainable chemistry conference successfully brings together scientists and innovators from all over the world to discuss sustainable chemistry

    Elschami, M. & Bazzanella, A., 02.2019, In: Current Opinion in Green and Sustainable Chemistry. 15, p. 115-117 3 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  48. Published

    The bispecific SDF1-GPVI fusion protein preserves myocardial function after transient ischemia in mice.

    Ziegler, M., Elvers, M., Baumer, Y., Leder, C., Ochmann, C., Schönberger, T., Jürgens, T., Geisler, T., Schlosshauer, B., Lunov, O., Engelhardt, S., Simmet, T. & Gawaz, M., 07.02.2012, In: Circulation. 125, 5, p. 685-696 12 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  49. Published

    The effect of storage medium on the elution of monomers from composite materials

    Polydorou, O., Huberty, C., Wolkewitz, M., Bolek, R., Hellwig, E. & Kümmerer, K., 27.01.2012, In: Journal of Biomedical Materials Research Part B: Applied Biomaterials. 100B, 1, p. 68-74 7 p.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  50. Published

    The lipid composition of the in situ pellicle

    Reich, M., Hannig, C., Hannig, M., Kümmerer, K. & Kensche, A., 01.10.2022, In: Archives of Oral Biology. 142, 105493.

    Research output: Journal contributionsJournal articlesResearchpeer-review

  51. Published

    The necessity of disinfected toilet brushes - information policy of companies on disinfectants in private homes

    Wieck, S., 23.01.2015, In: Environmental Sciences Europe. 27, 1, 9 p., 3.

    Research output: Journal contributionsJournal articlesResearchpeer-review