This paper proposes an Artificial Neural Network (ANN) to accurately predict the real angles obtained by a Triangulation Vision System. The performance of the ANN is compared with the K-Nearest Neighbors algorithm from previous publications. For the experimentation it was necessary to create a database to train and prove both methods in different coordinates on a determinate area through the dynamic triangulation method. Afterwards, the root mean square error is calculated to obtain the accuracy of each algorithm. Finally, several laser scanning measurements were taken at different distances to analyze the measurement dispersion of both algorithms.