Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes
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Authors
Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.
| Original language | English |
|---|---|
| Journal | Tetrahedron Letters |
| Volume | 23 |
| Issue number | 7 |
| Pages (from-to) | 719-722 |
| Number of pages | 4 |
| DOIs | |
| Publication status | Published - 1982 |
| Externally published | Yes |
- Chemistry