The 1,3 O→C silyl rearrangement of silyl enol ether anions - synthesis of α-silyl ketones.

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Silyl enol ethers with sterically hindered silyl groups are transformed into the corresponding α-silyl ketones by treatment with n-butyllithium/potassium tert-butylate.
Original languageEnglish
JournalTetrahedron Letters
Volume25
Issue number39
Pages (from-to)4345-4348
Number of pages4
DOIs
Publication statusPublished - 1984
Externally publishedYes