Nonylphenol polyethoxylate degradation by means of electrocoagulation and electrochemical Fenton

Research output: Journal contributionsJournal articlesResearchpeer-review

Authors

This study investigated the degradation of nonylphenol polyethoxylate (9 ethylene oxide unities, NP9EO) in aqueous solution and textile
wastewater by electrocoagulation (iron and aluminum electrodes) and electrochemical Fenton. The studied processes had as parameters NP9EO
concentration (measured by HPLC), chemical oxygen demand (COD), integrated absorbance (200–800 nm) and hydrogen peroxide concentration
(H2O2). First, it was determined the NP9EO concentration in textile wastewater by means of a modified procedure based on the extraction
of surfactants. A factorial design 24 was employed to optimize the experimental conditions for NP9EO degradation in aqueous solution by
electrocoagulation, through the following variables: NP9EO concentration, applied current, temperature and electrode material. The use of aluminum
electrodes brought the most significant effects. The best performance was achieved by experiments using 20 mg L−1 aqueous NP9EO, 1.5 A and
aluminum electrodes (around 95% removal in 30 min). The best experimental conditions achieved using factorial design were applied to textile
wastewater treatment. The electrocoagulation using Al-electrodes allowed the NP9EO degradation and COD reduction of 95 and 50%, respectively,
in only 15 min treatment. In order to enhance the aqueous NP9EO degradation obtained by electrocoagulation with iron electrodes, electrochemical
Fenton was also performed and 95% NP9EO removal was achieved in 5 min (aqueous solution) and 10 min (wastewater) treatment, respectively.
Besides the organic load removal (COD reduction) having not surpassed 55% in both processes, the total NP9EO removal of the textile wastewater
was equally efficient by both aqueous solution and textile wastewater treatment (causing almost total degradation).
Translated title of the contributionNonylphenol polyethoxilate Degradierung mittels Elektrocoagulation und elektrochemischen Fenton.
Original languageEnglish
JournalSeparation and Purification Technology
Volume50
Issue number2
Pages (from-to)249-255
Number of pages7
ISSN1383-5866
DOIs
Publication statusPublished - 15.06.2006

Bibliographical note

Funding Information:
The authors wish to thank the government agency CNPq/CT Hidro for the financial support and scholarships.

    Research areas

  • Chemistry - Electrochemical Fenton, Electrocoagulation, Nonylphenol polyethoxylate, Textile wastewater