Crystal structures of 1-2-(dicyclohexylphosphinophenyl)pyrol-2- dicyclohexylphosphino-rhodium(I) norborna-2,5-diene tetrafluoroborate tetrahydrofuran hemisolvate, [Rh(C 34H 5INP 2)(C 7H 8)] [BF 4] · 0.5C 4H 8O, and 1-2-(dicyclohexylphosphinophenyl)-pyrol-2- dicyclohexylphosphino-rhodium(I) (Z,Z)-cycloocta...
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Title full: Crystal structures of 1-2-(dicyclohexylphosphinophenyl)pyrol-2- dicyclohexylphosphino-rhodium(I) norborna-2,5-diene tetrafluoroborate tetrahydrofuran hemisolvate, [Rh(C 34H 5INP 2)(C 7H 8)] [BF 4] · 0.5C 4H 8O, and 1-2-(dicyclohexylphosphinophenyl)-pyrol-2- dicyclohexylphosphino-rhodium(I) (Z,Z)-cycloocta-1,5-diene tetrafluoroborate, [Rh(C 34H 5INP 2)(C 8H 12)] [BF 4]. C 43H 63BF 4NO 0.50P 2 Rh, monoclinic, P12 1/n1 (no. 14), a = 10.341(2) Å, b = 16.063(3) Å, c = 27.425(5) Å, β = 98.76(3)°, V= 4502.4 Å 3, Z = 4, R gt(F) = 0.060, wR ref(F 2) = 0.143, T = 200 K. C 42H 63BF 4NP 2Rh, monoclinic, P12 1/c1 (no. 14), a = 10.503(2) Å, b = 17.665(4) Å, c = 21.946(4) Å, β = 101.95(3)°, V= 3983.5 Å 3, Z = 4, R gt(F) = 0.045, wR ref(F 2) = 0.013, T =200 K.
| Original language | English |
|---|---|
| Journal | Zeitschrift für Kristallographie |
| Volume | 222 |
| Issue number | 4 |
| Pages (from-to) | 458-462 |
| Number of pages | 5 |
| DOIs | |
| Publication status | Published - 01.12.2007 |
| Externally published | Yes |
- Chemistry