Concentrations in ambient air and emissions of cyclic volatile methylsiloxanes in Zurich, Switzerland

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Concentrations in ambient air and emissions of cyclic volatile methylsiloxanes in Zurich, Switzerland. / Buser, Andreas M; Kierkegaard, Amelie; Bogdal, Christian et al.
In: Environmental Science & Technology, Vol. 47, No. 13, 02.07.2013, p. 7045-7051.

Research output: Journal contributionsJournal articlesResearchpeer-review

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Buser AM, Kierkegaard A, Bogdal C, MacLeod M, Scheringer M, Hungerbühler K. Concentrations in ambient air and emissions of cyclic volatile methylsiloxanes in Zurich, Switzerland. Environmental Science & Technology. 2013 Jul 2;47(13):7045-7051. doi: 10.1021/es3046586

Bibtex

@article{686cd4d95cde4743aac010060f75da9f,
title = "Concentrations in ambient air and emissions of cyclic volatile methylsiloxanes in Zurich, Switzerland",
abstract = "Tens of thousands of tonnes of cyclic volatile methylsiloxanes (cVMS) are used each year globally, which leads to high and continuous cVMS emissions to air. However, field measurements of cVMS in air and empirical information about emission rates to air are still limited. Here we present measurements of decamethylcyclopentasiloxane (D5) and dodecamethylcyclohexasiloxane (D6) in air for Zurich, Switzerland. The measurements were performed in January and February 2011 over a period of eight days and at two sites (city center and background) with a temporal resolution of 6-12 h. Concentrations of D5 and D6 are higher in the center of Zurich and range from 100 to 650 ng m(-3) and from 10 to 79 ng m(-3), respectively. These values are among the highest levels of D5 and D6 reported in the literature. In a second step, we used a multimedia environmental fate model parametrized for the region of Zurich to interpret the levels and time trends in the cVMS concentrations and to back-calculate the emission rates of D5 and D6 from the city of Zurich. The average emission rates obtained for D5 and D6 are 120 kg d(-1) and 14 kg d(-1), respectively, which corresponds to per-capita emissions of 310 mg capita(-1) d(-1) for D5 and 36 mg capita(-1) d(-1) for D6.",
keywords = "Chemistry, Air Pollutants, Cities, Environmental Monitoring, Models, Theoretical, Siloxanes, Switzerland",
author = "Buser, {Andreas M} and Amelie Kierkegaard and Christian Bogdal and Matthew MacLeod and Martin Scheringer and Konrad Hungerb{\"u}hler",
year = "2013",
month = jul,
day = "2",
doi = "10.1021/es3046586",
language = "English",
volume = "47",
pages = "7045--7051",
journal = "Environmental Science & Technology",
issn = "0013-936X",
publisher = "ACS Publications",
number = "13",

}

RIS

TY - JOUR

T1 - Concentrations in ambient air and emissions of cyclic volatile methylsiloxanes in Zurich, Switzerland

AU - Buser, Andreas M

AU - Kierkegaard, Amelie

AU - Bogdal, Christian

AU - MacLeod, Matthew

AU - Scheringer, Martin

AU - Hungerbühler, Konrad

PY - 2013/7/2

Y1 - 2013/7/2

N2 - Tens of thousands of tonnes of cyclic volatile methylsiloxanes (cVMS) are used each year globally, which leads to high and continuous cVMS emissions to air. However, field measurements of cVMS in air and empirical information about emission rates to air are still limited. Here we present measurements of decamethylcyclopentasiloxane (D5) and dodecamethylcyclohexasiloxane (D6) in air for Zurich, Switzerland. The measurements were performed in January and February 2011 over a period of eight days and at two sites (city center and background) with a temporal resolution of 6-12 h. Concentrations of D5 and D6 are higher in the center of Zurich and range from 100 to 650 ng m(-3) and from 10 to 79 ng m(-3), respectively. These values are among the highest levels of D5 and D6 reported in the literature. In a second step, we used a multimedia environmental fate model parametrized for the region of Zurich to interpret the levels and time trends in the cVMS concentrations and to back-calculate the emission rates of D5 and D6 from the city of Zurich. The average emission rates obtained for D5 and D6 are 120 kg d(-1) and 14 kg d(-1), respectively, which corresponds to per-capita emissions of 310 mg capita(-1) d(-1) for D5 and 36 mg capita(-1) d(-1) for D6.

AB - Tens of thousands of tonnes of cyclic volatile methylsiloxanes (cVMS) are used each year globally, which leads to high and continuous cVMS emissions to air. However, field measurements of cVMS in air and empirical information about emission rates to air are still limited. Here we present measurements of decamethylcyclopentasiloxane (D5) and dodecamethylcyclohexasiloxane (D6) in air for Zurich, Switzerland. The measurements were performed in January and February 2011 over a period of eight days and at two sites (city center and background) with a temporal resolution of 6-12 h. Concentrations of D5 and D6 are higher in the center of Zurich and range from 100 to 650 ng m(-3) and from 10 to 79 ng m(-3), respectively. These values are among the highest levels of D5 and D6 reported in the literature. In a second step, we used a multimedia environmental fate model parametrized for the region of Zurich to interpret the levels and time trends in the cVMS concentrations and to back-calculate the emission rates of D5 and D6 from the city of Zurich. The average emission rates obtained for D5 and D6 are 120 kg d(-1) and 14 kg d(-1), respectively, which corresponds to per-capita emissions of 310 mg capita(-1) d(-1) for D5 and 36 mg capita(-1) d(-1) for D6.

KW - Chemistry

KW - Air Pollutants

KW - Cities

KW - Environmental Monitoring

KW - Models, Theoretical

KW - Siloxanes

KW - Switzerland

U2 - 10.1021/es3046586

DO - 10.1021/es3046586

M3 - Journal articles

C2 - 23421312

VL - 47

SP - 7045

EP - 7051

JO - Environmental Science & Technology

JF - Environmental Science & Technology

SN - 0013-936X

IS - 13

ER -

DOI