This study addresses the impact of female Chief Executive Officers (CEOs) on corporate social responsibility (CSR) outcomes. Based on upper echelons theory, a structured literature review of empirical research on CEO gender, CSR performance, reporting, and assurance was conducted. Country-specific studies were differentiated according to their board structure and board gender quotas. This literature review indicates a positive impact of female CEOs on CSR performance in regimes with a one-tier system and voluntary board gender quotas. Research results on other regimes, other CSR outcomes, and cross-country designs are low in number or inconclusive. To the best of our knowledge, this is the first literature review with a focus on female CEOs and CSR. Key research gaps and recommendations for future research are mentioned, such as linking female CEOs with other demographic, social capital, and human capital attributes, including CSR reporting quality and moderator variables. Moreover, the study supports regulatory bodies and business practice to promote the selection of female CEOs for successful CSR transformation processes.