Biomass derived ionic liquids: synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes
Publikation: Beiträge in Zeitschriften › Zeitschriftenaufsätze › Forschung › begutachtet
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Biomass derived ionic liquids : synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes. / Ferlin, Nadège; Courty, Matthieu ; Gatard, Sylvain et al.
in: Tetrahedron, Jahrgang 69, Nr. 30, 29.07.2013, S. 6150 - 6161.Publikation: Beiträge in Zeitschriften › Zeitschriftenaufsätze › Forschung › begutachtet
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TY - JOUR
T1 - Biomass derived ionic liquids
T2 - synthesis from natural organic acids, characterization, toxicity, biodegradation and use as solvents for catalytic hydrogenation processes
AU - Ferlin, Nadège
AU - Courty, Matthieu
AU - Gatard, Sylvain
AU - Spulak, Marcel
AU - Quilty, Bríd
AU - Beadham, Ian G.
AU - Ghavre, Mukund
AU - Haiß, Annette
AU - Kümmerer, K.
AU - Gathergood, Nicholas
AU - Bouquillon, Sandrine
PY - 2013/7/29
Y1 - 2013/7/29
N2 - Ionic liquids with natural organic derived anions (l-lactate, l-tartrate, malonate, succinate, l-malate, pyruvate, d-glucuronate, d-galacturonate) were easily prepared from tetrabutylammonium hydroxide and an excess of the corresponding acid with good yields. Their characterization was realized through classical NMR, IR, and elemental analysis techniques; their viscosity and TGA (thermogravimetric analysis) parameters were also determined. These ionic liquids showed good performance and recyclability in the selective catalytic hydrogenation of 1,5-cyclooctadiene (1,5-COD) into cyclooctene (COD) at room temperature under atmospheric H 2 pressure. Antimicrobial toxicity assays toward a large panel of bacteria and fungi strains were also completed and biodegradation studies (Closed Bottle test, 28 days) were also performed.
AB - Ionic liquids with natural organic derived anions (l-lactate, l-tartrate, malonate, succinate, l-malate, pyruvate, d-glucuronate, d-galacturonate) were easily prepared from tetrabutylammonium hydroxide and an excess of the corresponding acid with good yields. Their characterization was realized through classical NMR, IR, and elemental analysis techniques; their viscosity and TGA (thermogravimetric analysis) parameters were also determined. These ionic liquids showed good performance and recyclability in the selective catalytic hydrogenation of 1,5-cyclooctadiene (1,5-COD) into cyclooctene (COD) at room temperature under atmospheric H 2 pressure. Antimicrobial toxicity assays toward a large panel of bacteria and fungi strains were also completed and biodegradation studies (Closed Bottle test, 28 days) were also performed.
KW - Biology
KW - Biodegradation
KW - Characterization
KW - Hydrogenation
KW - Ionic liquids
KW - Synthesis
KW - Toxicity
KW - Sustainability Science
UR - http://www.scopus.com/inward/record.url?scp=84878946691&partnerID=8YFLogxK
U2 - 10.1016/j.tet.2013.05.054
DO - 10.1016/j.tet.2013.05.054
M3 - Journal articles
VL - 69
SP - 6150
EP - 6161
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 30
ER -