A new way of assessing the interaction of a metallic phase precursor with a modified oxide support substrate as a source of information for predicting metal dispersion
Publikation: Beiträge in Zeitschriften › Zeitschriftenaufsätze › Forschung › begutachtet
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in: Arabian Journal of Chemistry, Jahrgang 13, Nr. 1, 01.01.2020, S. 2620-2627.
Publikation: Beiträge in Zeitschriften › Zeitschriftenaufsätze › Forschung › begutachtet
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TY - JOUR
T1 - A new way of assessing the interaction of a metallic phase precursor with a modified oxide support substrate as a source of information for predicting metal dispersion
AU - Nowicki, Waldemar
AU - Piskuła, Zbigniew
AU - Kirszensztejn, Piotr
AU - Bartkowiak, Dorota
AU - Kemnitz, Erhard
AU - Kuźma, Patrycja
PY - 2020/1/1
Y1 - 2020/1/1
N2 - Well-dispersed nanosized clusters of metallic platinum were obtained by decomposition of ethylenediamine complexes immobilized on amorphous silica surfaces. Samples before reduction were obtained by potentiometric titration in a heterogeneous liquid/solid system in different pH ranges. The proposed easy and inexpensive method for characterization of metal-ligand interactions provides new information about phenomena taking place at the molecular level, depending on the type of support, type of agent coupling with the ligand, and type of metal. The systems obtained were characterized by TEM, XRPD and hydrogen chemisorption. The catalytic properties of the systems studied were tested in N2O decomposition.
AB - Well-dispersed nanosized clusters of metallic platinum were obtained by decomposition of ethylenediamine complexes immobilized on amorphous silica surfaces. Samples before reduction were obtained by potentiometric titration in a heterogeneous liquid/solid system in different pH ranges. The proposed easy and inexpensive method for characterization of metal-ligand interactions provides new information about phenomena taking place at the molecular level, depending on the type of support, type of agent coupling with the ligand, and type of metal. The systems obtained were characterized by TEM, XRPD and hydrogen chemisorption. The catalytic properties of the systems studied were tested in N2O decomposition.
KW - Complexes on silica surface
KW - Metallic catalyst
KW - Platinum nanoparticles
KW - Silane coupling agent
KW - Chemistry
UR - http://www.scopus.com/inward/record.url?scp=85049473184&partnerID=8YFLogxK
U2 - 10.1016/j.arabjc.2018.06.015
DO - 10.1016/j.arabjc.2018.06.015
M3 - Journal articles
AN - SCOPUS:85049473184
VL - 13
SP - 2620
EP - 2627
JO - Arabian Journal of Chemistry
JF - Arabian Journal of Chemistry
SN - 1878-5352
IS - 1
ER -